No villain actually ever thinks of themselves as the "villain" -- in fact, from their perspective, they often think they are the 'good guy' and have multiple goals/agendas of their own that they want to fulfill.
Sure, one of those goals might be CONQUERING ALL OF EORZEA AND CRUSHING THE HEARTS OF CHILDREN AND KITTENS EVERYWHERE, but all their other goals might be more interaction-friendly. For example one might be that they need some kind of device constructed and thus have to chat and make connections with engineer-type characters. Or maybe want bodyguards and decide to chat some folks up to see if they're hire-able. Or maybe they see one of the good guys and simply find them to be an interesting person to talk to.
I think it's helpful to think of your villain less as purely a bad guy, but as a character just like any other character. Every character has reasons they may or may not want to chat or interact with folks. Hell, some villains are not even outright jerks on the surface and are actually incredibly likable people, they just have ultimate goals that stick them in the 'villain' category compared to most folks in Eorzea.
Sure, one of those goals might be CONQUERING ALL OF EORZEA AND CRUSHING THE HEARTS OF CHILDREN AND KITTENS EVERYWHERE, but all their other goals might be more interaction-friendly. For example one might be that they need some kind of device constructed and thus have to chat and make connections with engineer-type characters. Or maybe want bodyguards and decide to chat some folks up to see if they're hire-able. Or maybe they see one of the good guys and simply find them to be an interesting person to talk to.
I think it's helpful to think of your villain less as purely a bad guy, but as a character just like any other character. Every character has reasons they may or may not want to chat or interact with folks. Hell, some villains are not even outright jerks on the surface and are actually incredibly likable people, they just have ultimate goals that stick them in the 'villain' category compared to most folks in Eorzea.