Admittedly, this isn't 'true' acapella since they do use one instrument. (Drums). But I think they deserve a place here for being the only Metal acapella band in existence as far as I know. I'm not a fan of Metallica personally, but this song shows how amazing they are at what they do.
Van Canto
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And then this one is my personal favorite (and also the first song I ever heard by them.)
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Van Canto
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And then this one is my personal favorite (and also the first song I ever heard by them.)
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-Ceadol Sacamar, Conjurer Extrordinaire!